Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates

G. A. Molander; N. Fleury-Brégeot; M.-A. Hiebel

doi:10.1055/s-0030-1259899

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Synfacts 2011(6): 0666-0666
DOI: 10.1055/s-0030-1259899

Metal-Mediated Synthesis

Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates

Contributor(s): Paul Knochel, Andreas J. Wagner
G. A. Molander*, N. Fleury-Brégeot, M.-A. Hiebel
University of Pennsylvania, Philadelphia, USA

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Publication History

Publication Date:
19 May 2011 (online)

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Significance

The palladium-catalyzed cross-coupling of various functionalized sulfonamidomethyltrifluoroborates with a large range of aryl and heteroaryl halides and pseudohalides affords the corresponding benzylic sulfonamides in high yields.