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Synfacts 2011(1): 0111-0111
DOI: 10.1055/s-0030-1259135
DOI: 10.1055/s-0030-1259135
Polymer-Supported Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Photocatalytic Aerobic Oxidation of Alcohols on TiO2
Q. Wang, M. Zhang, C. Chen, W. Ma, J. Zhao*
Institute of Chemistry, Chinese Academy of Sciences, Beijing and Zhejiang Gongshang University, Hangzhou, P. R. of China
Further Information
Publication History
Publication Date:
21 December 2010 (online)
Significance
Photocatalytic aerobic oxidation of alcohols was efficiently performed on H+/SiO2/TiO2. H+/SiO2/TiO2 was prepared by treatment of SiO2/TiO2 with a Brønsted acid, which exhibited good catalytic performance for the oxidation of alcohols to give the corresponding aldehydes or ketones (5 examples, 85-100% conversion, 87-100% selectivity).