Homoaldol Equivalent Reaction between a Nucleophilic Propenyl
Acetate and Aldehydes

doi:10.1055/s-0030-1257895

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Synfacts 2010(9): 1063-1063
DOI: 10.1055/s-0030-1257895

Metal-Mediated Synthesis

Homoaldol Equivalent Reaction between a Nucleophilic Propenyl Acetate and Aldehydes

Contributor(s): Paul Knochel, Tobias Thaler
J. Y. Kang, B. T. Connell*
Texas A&M University, College Station, USA

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Publikationsverlauf

Publikationsdatum:
23. August 2010 (online)

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Significance

A highly regioselective and stereoselective catalytic homoaldol equivalent reaction between 3-bromopropenyl acetate and an aldehyde using Cr/Mn redox conditions is reported. The reaction proceeds under mild conditions tolerating functional groups, such as ethers and ketones.