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DOI: 10.1055/s-0029-1219074
An Insulated Conjugated Polymer Wire
Contributor(s):Timothy M. Swager, Jan M. SchnorrKyoto University, PRESTO, Japan Science and Technology Agency, Kyoto, Osaka University and Tokyo Institute of Technology, Japan
Synthesis of Organic-Soluble Conjugated Polyrotaxanes by Polymerization of Linked Rotaxanes
J. Am. Chem. Soc. 2009, 131: 16004-16005
Publication History
Publication Date:
21 January 2010 (online)
Key words
polyrotaxanes - host-guest systems - conjugated polymers
Significance
Insulated molecular wires are an interesting target for molecular electronics. The authors synthesize such a structure (5) by polymerizing 4, in which a conjugated unit is surrounded by a permethylated α-cyclodextrin (PM α-CD). Intermediate 3 is obtained using a recently reported route (S. Tsuda, J. Terao, N. Kambe Chem. Lett. 2009, 38, 76).
Comment
Polymer 6 containing repeat units with two PM α-CD moieties was synthesized using the same strategy. Compared to the equivalent in which PM α-CD units are attached at the same positions but not including the conjugated system through a host-guest pair, it shows a significantly higher solid-state quantum yield (23% vs. 6%). This suggests shielding of the molecular wire in 6.