Direct Synthesis of Phenanthridines via Domino Arylation/N-Arylation

doi:10.1055/s-0029-1218043

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Synfacts 2009(11): 1266-1266
DOI: 10.1055/s-0029-1218043

Metal-Mediated Synthesis

Direct Synthesis of Phenanthridines via Domino Arylation/N-Arylation

Contributor(s): Paul Knochel, Tobias Thaler
D. A. Candito, M. Lautens*
University of Toronto, Canada

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Publikationsdatum:
22. Oktober 2009 (online)

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Significance

An efficient method for the preparation of variously substituted phenanthridines and benzo[c]phenanthridines using a variation of the Catellani reaction was developed. Hereby, N-unsubstituted and N-silylamidines are arylated.