Allylation and Crotylation of Carbonyls Using Organotrifluoroborates

doi:10.1055/s-0029-1217765

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook Linkedin Weibo

Download PDF

Synfacts 2009(9): 1021-1021
DOI: 10.1055/s-0029-1217765

Metal-Mediated Synthesis

Allylation and Crotylation of Carbonyls Using Organotrifluoroborates

Contributor(s): Paul Knochel, Tobias Thaler
F. Nowrouzi, A. N. Thadani, R. A. Batey*
University of Toronto, Canada

Further Information

Publication History

Publication Date:
21 August 2009 (online)

Permissions and Reprints

Significance

In this article two novel protocols for the diastereoselective allylation and crotylation of ketones using air- and water-stable allyl- and crotyltrifluoroborates are reported. BF₃˙OEt₂ or montmorillonite are hereby used as efficient catalysts.