Heck Reaction with SBA-15-Supported Palladium Catalyst

J.-Y. Jung; A. Taher; H.-J. Kim; W.-S. Ahn; M.-J. Jin

doi:10.1055/s-0028-1087859

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Synfacts 2009(4): 0454-0454
DOI: 10.1055/s-0028-1087859

Polymer-Supported Synthesis

Heck Reaction with SBA-15-Supported Palladium Catalyst

Contributor(s): Yasuhiro Uozumi, Go Hamasaka
J.-Y. Jung, A. Taher, H.-J. Kim, W.-S. Ahn, M.-J. Jin*
Inha University, Incheon, Korea

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Publication History

Publication Date:
23 March 2009 (online)

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Significance

SBA-15-supported ionic liquid-Pd(OAc)₂ 3 was prepared by the immobilization of ionic liquid 1 onto SBA-15, followed by the treatment with Pd(OAc)₂ and ionic liquid [BMI][PF₆]. Heck reaction of aryl halides 4 with acrylates 5 was carried out with 1 mol% Pd of 3 in the presence of Bu₃N to give the styrene derivatives 6 in 21-100% yield.