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Synfacts 2008(6): 0560-0560  
DOI: 10.1055/s-2008-1072598
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart · New York

Formal Synthesis of Callipeltoside Aglycone

Contributor(s): Philip Kocienski, Stewart Eccles
J. A. Marshall*, P. M. Eidam
University of Virginia, Charlottesville, USA
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Publikationsdatum:
21. Mai 2008 (online)

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Significance

This formal synthesis of callipeltoside uses a Nozaki-Hiyama-Kishi (NHK) reaction to install the allylic alcohol in C and a macrolactonization of the acyl ketene intermediate F.