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Synfacts 2007(12): 1286-1286  
DOI: 10.1055/s-2007-991369
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Palladium-Catalyzed Asymmetric Diamination

Contributor(s): Mark Lautens, Praew Thansandote
H. Du, W. Yuan, B. Zhao, Y. Shi*
Colorado State University, Fort Collins, USA
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Publikationsdatum:
22. November 2007 (online)

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Significance

Following up on their recent publications on the Pd-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes (H. Du, B. Zhao, Y. Shi. J. Am. Chem. Soc. 2007, 129, 762; H. Du, W. Yuan, B. Zhao, Y. Shi J. Am. Chem. Soc. 2007, 129, 7496), the authors report the first catalytic asymmetric version of this reaction.