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Synfacts 2007(9): 0895-0895
DOI: 10.1055/s-2007-968841
DOI: 10.1055/s-2007-968841
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart · New York
Synthesis of Baconipyrone C
D. G. Gillingham, A. H. Hoveyda*
Boston College, Chestnut Hill, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
23. August 2007 (online)
Significance
A new chiral Ru-based N-heterocyclic carbene complex F was deployed in the first asymmetric Ru-catalyzed asymmetric olefin metathesis reaction (E to G). New Ag- and Cu-based N-heterocyclic carbene complexes were used in catalytic asymmetric allylic alkylation reactions (e.g. A to C).