One-Step Substitutive Acyloxylation at Carbon. Part II. Reactions Involving Metal Salts

David J. RAWLINSON; George SOSNOVSKY

doi:10.1055/s-1973-22262

Synthesis 1973; 1973(10): 567-603
DOI: 10.1055/s-1973-22262

review

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One-Step Substitutive Acyloxylation at Carbon. Part II. Reactions Involving Metal Salts

David J. RAWLINSON^* , George SOSNOVSKY

^*Department of Chemistry, Western Illinois University, Macomb, Illinois 61455, U. S. A.

Abstract

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Methods of direct introduction of the acyloxy group in place of hydrogen attached to carbon are described. This review covers reactions involving the metal salts: lead(IV) acetate, mercury(II) acetate, thallium(III) acetate, palladium salts, and others. Acyloxylations, using metal salts, of hydrocarbons, carbonyl and carboxylic acid derivatives, ethers, thioethers, and some other compounds are included. 1. Acyloxylations with Lead(IV) Acetate 2. Acyloxylations with Mercury(II) Acetate 3. Acyloxylations with Thallium(III) Acetate 4. Acyloxylations with Palladium Salts 5. Miscellaneous Acyloxylation Reactions

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