Silanediol Anion Binding and Enantioselective Catalysis

Jonathan W. Attard; Kohei Osawa; Yong Guan; Jessica Hatt; Shin-ichi Kondo; Anita Mattson

doi:10.1055/s-0037-1612217

Synthesis, Table of Contents

Synthesis 2019; 51(10): 2107-2115
DOI: 10.1055/s-0037-1612217

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Silanediol Anion Binding and Enantioselective Catalysis

Jonathan W. Attard

^aWorcester Polytechnic Institute, Department of Chemistry and Biochemistry, Worcester, MA 01609, USA Email: aemattson@wpi.edu

,

Kohei Osawa

^bYamagata University, Department of Biochemical Engineering, Graduate School of Science and Engineering, Yonezawa, Yamagata 992-8510, Japan

,

Yong Guan

^aWorcester Polytechnic Institute, Department of Chemistry and Biochemistry, Worcester, MA 01609, USA Email: aemattson@wpi.edu

,

Jessica Hatt

^aWorcester Polytechnic Institute, Department of Chemistry and Biochemistry, Worcester, MA 01609, USA Email: aemattson@wpi.edu

,

Shin-ichi Kondo

^bYamagata University, Department of Biochemical Engineering, Graduate School of Science and Engineering, Yonezawa, Yamagata 992-8510, Japan

,

Anita Mattson*

^aWorcester Polytechnic Institute, Department of Chemistry and Biochemistry, Worcester, MA 01609, USA Email: aemattson@wpi.edu

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Abstract

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Abstract

Silanediols possess unique and complementary catalytic activity in reactions that are likely to proceed through anion binding. This article directly compares silanediols, thioureas, and squaramides in three separate anion-binding processes. The catalytic abilities of select members of each family are directly correlated to association constants.

Key words

anion recognition - enantioselective catalysis - thiourea - silanediol - squaramide

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References

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