A transition-metal-free heterocyclization of 1,3-diynes and nitriles in the presence
               of either aqueous potassium hydroxide or cesium hydroxide in 1,4-dioxane at 100 °C
               was realized. This method provided stereoselectively 2,4-disubstituted 5-[(E)-2-phenylethenyl]-1,3-oxazoles in moderate to good yields. 
            
         Key words
1,3-diyne - nitrile - heterocyclization - cesium hydroxide - potassium hydroxide