High-Pressure Transformations in Natural Product Synthesis

Cedric L. Hugelshofer; Thomas Magauer

doi:10.1055/s-0033-1341073

Synthesis, Inhaltsverzeichnis

Synthesis 2014; 46(10): 1279-1296
DOI: 10.1055/s-0033-1341073

review

High-Pressure Transformations in Natural Product Synthesis

Cedric L. Hugelshofer

Department of Chemistry, Ludwig-Maximilians-Universität Munich, Butenandtstraße 5–13, 81377 Munich, Germany Fax: +49(89)218077864 eMail: thomas.magauer@lmu.de

,

Thomas Magauer*

Department of Chemistry, Ludwig-Maximilians-Universität Munich, Butenandtstraße 5–13, 81377 Munich, Germany Fax: +49(89)218077864 eMail: thomas.magauer@lmu.de

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Abstract

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Abstract

This review summarizes the application of high-pressure chemistry in natural product synthesis. By highlighting reactions that could not be promoted by conventional means but that proceed readily under high-pressure conditions, we intend to disclose the benefits of high-pressure-mediated reactions for organic transformations. The individual syntheses are classified by the reaction type of the key step and are discussed briefly.

1 Introduction

2 Cycloaddition Reactions

2.1 Diels–Alder Reactions

2.2 Inverse-Electron-Demand Diels–Alder Reactions

2.3 Hetero-Diels–Alder Reactions

3 Miscellaneous Reactions

4 Conclusion

Key words

high pressure - natural products - Diels–Alder reaction - total synthesis - asymmetric synthesis

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Referenzen

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