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Synfacts 2011(11): 1200-1200  
DOI: 10.1055/s-0031-1289182
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Iron-Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols

Contributor(s): Hisashi Yamamoto, Kimberly Griffin
T. Kunisu, T. Oguma, T. Katsuki*
Kyushu University, Fukuoka, Japan
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Publication History

Publication Date:
19 October 2011 (online)

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Significance

A recent shift from applying less common transition metals as catalysts has increased the use of iron as a catalyst. Herein, a general method for iron-catalyzed aerobic oxidative kinetic resolution of secondary alcohols is described. The reaction proceeds in air, further enhancing the environmental appeal of this method.