Ni-Mediated Decarbonylative Cross-Coupling of Diorganozinc
Reagents

S. E. Havlik; J. M. Simmons; V. J. Winton; J. B. Johnson

doi:10.1055/s-0030-1260725

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Synfacts 2011(8): 0889-0889
DOI: 10.1055/s-0030-1260725

Metal-Mediated Synthesis

Ni-Mediated Decarbonylative Cross-Coupling of Diorganozinc Reagents

Contributor(s): Paul Knochel, Andreas J. Wagner
S. E. Havlik, J. M. Simmons, V. J. Winton, J. B. Johnson*
Hope College, Holland, USA

Further Information

Publication History

Publication Date:
20 July 2011 (online)

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Significance

A nickel-mediated decarbonylative cross-coupling of various phthalimides with diorganozinc reagents to give ortho-substituted benzamides is reported. Alkyl and aryl diorganozincs are viable substrates and the product yields are high.