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Synfacts 2011(1): 0082-0082
DOI: 10.1055/s-0030-1259110
DOI: 10.1055/s-0030-1259110
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New YorkArylation of α-Chiral Ketones via
Cross-Coupling
of Tosylhydrazones
J. Barluenga*, M. Escribano, F. Aznar, C. Valdés*
Universidad de Oviedo, Spain
Further Information
Publication History
Publication Date:
21 December 2010 (online)
Significance
The palladium-catalyzed arylation of tosylhydrazones derived from cyclohexanones and methyl ketones was shown to proceed highly regioselectively, furnishing the less substituted alkenes.