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Synfacts 2010(6): 0704-0704
DOI: 10.1055/s-0029-1219767
DOI: 10.1055/s-0029-1219767
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
1,4-Disubstituted 5-Alumino-1,2,3-triazoles from Aluminum Acetylides and Azides
Y. Zhou, T. Lecourt, L. Micouin*
Université Paris Descartes, France
Further Information
Publication History
Publication Date:
20 May 2010 (online)
Significance
A copper-catalyzed cycloaddition of organic azides to dialkyl aluminum acetylides is reported. The regioselectivity of the reaction combined with the reactivity of the final aluminotriazoles enables a rapid and convenient access to 1,4,5-trisubstituted triazoles.