Lewis Acid Catalyzed Direct Intramolecular Amination of Allylic
Alcohols

N. Kawai; R. Abe; J. Uenishi

doi:10.1055/s-0029-1219098

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Synfacts 2010(2): 0184-0184
DOI: 10.1055/s-0029-1219098

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Lewis Acid Catalyzed Direct Intramolecular Amination of Allylic Alcohols

Contributor(s): Hisashi Yamamoto, Zhi Li
N. Kawai*, R. Abe, J. Uenishi
Kyoto Pharmaceutical University, Japan

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Publikationsverlauf

Publikationsdatum:
21. Januar 2010 (online)

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Significance

The authors designed a very efficient Lewis acid catalyzed pathway for the direct intramolecular S_N2′ amination of allylic alcohols. The reaction is proposed to undergo a chelation intermediate of bismuth(III) ion and the substrate.