Ir-Catalyzed Cross-Coupling of Styrene Derivatives with Allylic
Carbonates

doi:10.1055/s-0029-1217639

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Synfacts 2009(9): 0987-0987
DOI: 10.1055/s-0029-1217639

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Ir-Catalyzed Cross-Coupling of Styrene Derivatives with Allylic Carbonates

Contributor(s): Mark Lautens, Jacki Kitching
H. He, W.-B. Liu, L.-X. Dai, S.-L. You*
Shanghai Institute of Organic Chemistry, P. R. of China

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Publication History

Publication Date:
21 August 2009 (online)

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Significance

The iridium-catalyzed cross-coupling of o-amino-styrene derivatives with allylic carbonates is described. The procedure affords skipped Z,E-dienes with the exclusive formation of a cis double bond.