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Synfacts 2009(3): 0321-0321
DOI: 10.1055/s-0028-1087713
DOI: 10.1055/s-0028-1087713
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Pd Nanoparticle Catalyzed Allyl Cross-Coupling of Siloxanes
R. Dey, K. Chattopadhyay, B. C. Ranu*
Indian Association for the Cultivation of Science, Kolkata, India
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
19. Februar 2009 (online)

Significance
The authors present herein a cross-coupling reaction of allyl acetates and aryl or vinyl siloxanes catalyzed by in situ generated palladium nanoparticles. This cross-coupling proceeds in refluxing tetrahydrofuran and affords the respective arylated or vinylated olefins in generally very good yields.