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Synfacts 2009(3): 0321-0321  
DOI: 10.1055/s-0028-1087713
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Pd Nanoparticle Catalyzed Allyl Cross-Coupling of Siloxanes

Contributor(s): Paul Knochel, Andreas J. Wagner
R. Dey, K. Chattopadhyay, B. C. Ranu*
Indian Association for the Cultivation of Science, Kolkata, India
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Publikationsverlauf

Publikationsdatum:
19. Februar 2009 (online)

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Significance

The authors present herein a cross-coupling reaction of allyl acetates and aryl or vinyl siloxanes catalyzed by in situ generated palladium nanoparticles. This cross-coupling proceeds in refluxing tetrahydrofuran and affords the respective arylated or vinylated olefins in generally very good yields.