Heterogeneous Hydrogenation of Quinoline Derivatives Effected by a Granular Cobalt Catalyst

Daniel Timelthaler; Christoph Topf

doi:10.1055/a-1654-3302

Synthesis, Inhaltsverzeichnis

CC BY 4.0 · Synthesis 2022; 54(03): 629-642
DOI: 10.1055/a-1654-3302

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Heterogeneous Hydrogenation of Quinoline Derivatives Effected by a Granular Cobalt Catalyst

Authors

Daniel Timelthaler
Christoph Topf∗

Abstract

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Abstract

We communicate a convenient method for the pressure hydrogenation of quinolines in aqueous solution by using a particulate cobalt-based catalyst that is prepared in situ from simple Co(OAc)₂·4H₂O through reduction with abundant zinc powder. This catalytic protocol permits a brisk and atom-efficient access to a variety of 1,2,3,4-tetrahydroquinolines thereby relying solely on easy-to-handle reagents that are all readily obtained from commercial sources. Both the reaction setup assembly and the autoclave charging procedure are conducted on the bench outside an inert-gas-operated containment system, thus rendering the overall synthesis time-saving and operationally very simple.

Key words

heterogeneous catalysis - hydrogenation - cobalt - zinc - tetrahydroquinolines

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