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Synlett 2010(8): 1201-1204  
DOI: 10.1055/s-0029-1219811
LETTER
© Georg Thieme Verlag Stuttgart ˙ New York

Fast, Efficient, and Convenient Method for the Preparation of Arylazo Aryl Sulfones Using Stable Aryldiazonium Silica Sulfates under Mild Conditions

Amin Zarei*a, Abdol R. Hajipourb,c, Leila Khazdoozd, Hamidreza Aghaeie
a Department of Science, Islamic Azad University, Fasa Branch, PO Box No. 364, Fasa 7461713591, Fars, Iran
Fax: +98(311)2289113; e-Mail: aj_zarei@yahoo.com;
b Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, Iran
c Department of Pharmacology, University of Wisconsin, Medical School, 1300 University Avenue, Madison WI 53706-1532, USA
d Department of Science, Islamic Azad University, Khorasgan Branch, Isfahan 81595-158, Iran
e Department of Chemistry, Islamic Azad University, Shahreza Branch, Shahreza 311-86145, Isfahan, Iran
Further Information

Publication History

Received 3 November 2009
Publication Date:
09 April 2010 (online)

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Abstract

An efficient, fast, and straightforward procedure for the synthesis of arylazo aryl sulfones is described by using aryl diazonium silica sulfates and sodium arenesulfinates. The reaction was carried out at room temperature under mild conditions. The use of inexpensive materials, simple and clean workup, short reaction times, and good yields are the advantages of this method.

Key words

aryl diazonium silica sulfates - sodium arenesulfinates - arylazo aryl sulfones

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