TY - JOUR AU - Miyagawa, Masamichi; Yamamoto, Ryota; Kobayashi, Nanako; Akiyama, Takahiko TI - Reduction of Nitroarenes to Anilines with a Benzothiazoline: Application to Enantioselective Synthesis of 2-Arylquinoline Derivatives SN - 0936-5214 SN - 1437-2096 PY - 2019 JO - Synlett JF - Synlett LA - EN VL - 30 IS - 04 SP - 499 EP - 502 ET - 2018/12/17 DA - 2019/02/15 KW - benzothiazolines KW - phosphoric acids KW - isoquinolines KW - nitro­arenes KW - anilines KW - reduction AB - The metal-free reduction of nitroarenes to aniline derivatives was accomplished in a short time by using a benzothiazoline as the hydrogen donor in combination with a Brønsted acid. An enantioselective synthesis of 2-arylquinolines was achieved by using 1-aryl-3-(2-nitrophenyl)propan-1-ones as starting materials and a combination of a benzothiazoline and a chiral phosphoric acid. PB - Georg Thieme Verlag DO - 10.1055/s-0037-1611639 UR - http://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0037-1611639 ER -