TY - JOUR AU - Evano, Gwilherm; Lecomte, Morgan; Thilmany, Pierre; Theunissen, Cédric TI - Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis SN - 0039-7881 SN - 1437-210X PY - 2017 JO - Synthesis JF - Synthesis LA - EN VL - 49 IS - 15 SP - 3183 EP - 3214 ET - 2017/07/17 DA - 2017/07/19 KW - keteniminium ions KW - ketenimines KW - ynamines KW - ynamides KW - amides KW - reactive intermediates AB - Keteniminium ions have been demonstrated to be remarkably useful and versatile reactive intermediates in chemical synthesis. These unique heterocumulenes are pivotal electrophilic species involved in a number of efficient and selective transformations. More recently, even more reactive ‘activated’ keteniminium ions bearing an additional electron-withdrawing group on the nitrogen atom have been extensively investigated. The chemistry of these unique reactive intermediates, including representative methods for their in situ generation, will be overviewed in this review article.1 Introduction2 The Chemistry of Keteniminium Ions3 The Chemistry of Activated Keteniminium Ions4 Keteniminium Ions: Pivotal Intermediates for the Synthesis of Natural and/or Biologically Relevant Molecules5 Conclusions and Perspectives PB - © Georg Thieme Verlag DO - 10.1055/s-0036-1588452 UR - http://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1588452 ER -