TY - JOUR AU - Chen, Xiaolei; He, Shanshan; Shen, Subo; Zhao, Jingwei; Zhang, Jianmin; Zhu, Shizheng TI - Synthesis of Fullerene-Fused Fluorine-Containing Lactones from the Radical Reaction of [60]Fullerene with Fluorinated Phenylacetic Acids SN - 0039-7881 SN - 1437-210X PY - 2012 JO - Synthesis JF - Synthesis LA - EN VL - 44 IS - 15 SP - 2347 EP - 2352 ET - 2012/06/18 DA - 2012/07/20 KW - C60-fused lactones KW - fluorinated phenylacetic acids KW - manganese(III) acetate KW - stereoisomers AB - A series of fullerene-fused fluorinated lactones were prepared­ by the manganese(III) acetate mediated radical reaction of [60]fullerene (C60) with fluorinated phenylacetic acids (ArFCH2COOH). Interestingly, the products which contain a 2-fluoro­ substituent on the benzene ring are mixtures of two stereoisomers due to the stereo and electronic effects of the ortho-fluorine atom­. PB - © Georg Thieme Verlag DO - 10.1055/s-0031-1290409 UR - http://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0031-1290409 ER -