Total Synthesis of (–)-FR182877 (Synfacts, 2025)
Keywords: (–)-FR182877; polyketide synthesis; Suzuki–Miyaura coupling; Roskamp homologation; Appel reaction; macrocylization; transannular Diels–Alder reaction; inverse-electron-demand hetero-Diels–Alder reaction; Suzuki methylenation; Mukaiyama lactonization