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Synfacts 2007(10): 1055-1055  
DOI: 10.1055/s-2007-969016
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Novel Carbohydrate-Based Ligands for 1,4-Addition Reactions

Contributor(s): Hisashi Yamamoto, Marina Naodovic
Y. Mata, M. DiÉguez*, O. PÀimies*, K. Biswas, S. Woodward*
universitat Rovira I Virgili, Tarragona, Spain and The University of Notthingham, UK
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Publication History

Publication Date:
07 November 2007 (online)

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Significance

Herein, new ligands for less-explored conjugated addition of organoalu­minum reagents are described. Carbohydrate phosphite-oxazoline and -phosphoroamidite ligands are shown to be very efficient ligands for Cu-catalyzed addition of alkylaluminum nucleophiles to cyclic and acyclic enones.