Fe(II)-Catalyzed sp3-sp3 Cross-Coupling Reactions

K. G. Dongol; H. Koh; M. Sau; C. L. L. Chai

doi:10.1055/s-2007-968748

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Synfacts 2007(8): 0858-0858
DOI: 10.1055/s-2007-968748

Metal-Mediated Synthesis

Fe(II)-Catalyzed sp³-sp³ Cross-Coupling Reactions

Contributor(s): Paul Knochel, Tobias Thaler
K. G. Dongol, H. Koh, M. Sau, C. L. L. Chai*
Institute of Chemical and Engineering Sciences, Singapore

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Publication History

Publication Date:
24 July 2007 (online)

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Significance

This study represents the first exploitation of an sp³-sp³ cross-coupling reaction between unactivated primary alkyl bromides and primary alkylmagnesium bromides. It is an enrichment to the field of iron catalysis.