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Synfacts 2007(2): 0184-0184  
DOI: 10.1055/s-2006-955840
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Addition of Enecarbamates and Enamides to Iminophosphonates

Contributor(s): Hisashi Yamamoto, Joshua P. Abell
H. Kiyohara, R. Matsubara, S. Kobayashi*
The University of Tokyo, Japan
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Publication History

Publication Date:
23 January 2007 (online)

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Significance

This paper describes the continued work in the development of enantiomercially enriched α-amino phosphonates. Previously the authors utilized a highly reactive silicon enolate to iminophosphonates. The problems of the previous method are overcome in this new protocol.