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Synthesis 2003(4): 0593-0597
DOI: 10.1055/s-2003-37662
PAPER
© Georg Thieme Verlag Stuttgart · New York

A Novel Ring Transformation of Nitrobenzocrown Ethers as a Route to Nitrobenzoazacrown Compounds

Sergey P. Gromov*, Svetlana N. Dmitrieva, Marina V. Churakova
Photochemistry Center of the Russian Academy of Sciences, ul. Novatorov 7a, Moscow 119421, Russia
Fax: +7(095)9361255; e-Mail: gromov@photonics.ru;
Further Information

Publication History

Received 25 October 2002
Publication Date:
07 March 2003 (online)

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Abstract

A method for the synthesis of previously unknown nitro derivatives of benzoazacrown compounds in which nitrogen is conjugated with the benzene ring, based on readily available benzocrown ethers used as synthons, has been developed. This approach can serve as a useful tool in the synthesis of diverse benzoazacrown derivatives.

Key words

ring opening - crown compounds - podands - ring closure - nitrobenzoazacrown compounds

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