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Synlett 2001; 2001(5): 0688-0690
DOI: 10.1055/s-2001-13384
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A New Convenient Method for the Generation of Alkoxy Radicals from N-Alkoxydithiocarbamates

Sunggak Kim* , Chae Jo Lim, Sang-Eun Song, Han-Young Kang
  • *Center of Molecular Design and Synthesis and Department of Chemistry, School of Molecular Science, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea; Fax + 82-42-869-8370; E-mail: skim@mail.kaist.ac.kr
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Publication Date:
31 December 2001 (online)

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N-Alkoxydithiocarbamates 2, which can be conveniently prepared from alkyl halides or alcohols using N-methylhydroxy-dithiocarbamate 1, are very useful precursors of alkoxy radicals.

radicals - alcohols - alkyl halides - alkoxy radicals - thiohydroxamates

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