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Synlett 2001; 2001(5): 0634-0636
DOI: 10.1055/s-2001-13361
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Synthesis of Thiophene-Based Building Blocks via Facile α-Monoiodination

Ulrik Boas* , Anantharaman Dhanabalan, Daniel R. Greve, E. W. Meijer
  • *Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box. 513, 5600 MB Eindhoven, The Netherlands; E-mail: e.w.meijer@tue.nl
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Publication Date:
31 December 2001 (online)

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A new procedure to selectively α-monoiodinate symmetrical thiophene-capped segments is described. The monoiodinated derivatives are further modified, giving access to a variety of thiophene-based building blocks, which are useful for e.g. oligomer synthesis via segmental coupling.

monoiodination - N-iodosuccinimide - oligothiophenes - thiophene-based segments

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