Download PDF
Synlett 2001; 2001(4): 0505-0508
DOI: 10.1055/s-2001-12312
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Iodosobenzene and Iodoxybenzene as Reagents for Oxygen Transfer in Organophosphorus Chemistry

Grażyna Mielniczak* , Andrzej Łopusiński
  • *Center of Molecular and Macromolecular Studies Polish Academy of Science, Sienkiewicza 112, 90-363 Łódź, Poland; E-mail: lopuch@bilbo.cbmm.lodz.pl
Further Information

Publication History

Publication Date:
31 December 2001 (online)

  PDF Download  Permissions and Reprints All articles of this category

The application of iodosobenzene (1) and iodoxybenzene (2) for the oxidation reaction of phosphorus, phosphorothiono and phosphoroseleno compounds into the corresponding ≡P(O) analogs is demonstrated. Retention of configuration at the phosphorus atom and full stereoselectivity of these reactions in model diastereoisomeric cis- and trans-2-phenylamino-2-thiono-4-methyl-1.3.2-dioxaphosphorinans (30) as well cis- and trans-2-phenylamino-2-seleno-4-methyl-1.3.2-dioxaphosphorinans (31) systems, are demonstrated.

oxidation - iodosobenzene - iodoxybenzene - organophosphates

      >