Download PDF
Synthesis 2000; 2000(1): 139-143
DOI: 10.1055/s-2000-6218
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Stepwise α-Bromination of 1,1-Dihaloalkenes

Shengming Ma* , Bin Xu, Shimin Zhao
  • *Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354, Fenglin Lu, Shanghai 200032, P. R. China; Fax +86 (21) 64 16 61 28; E-mail: masm@pub.sioc.ac.cn
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A series of 1,1-dihaloalkenes were stepwise brominated using N-bromosuccinimide (NBS) under the catalysis of benzoyl peroxide (BPO) to afford the corresponding bromination products in moderate to high yields.

stepwise α-bromination - gem-dihaloalkenes - N-bromosuccinimide - Wohl - Ziegler reaction - allylic bromide - halides - radical reactions

      >