Download PDF
Synlett 1999; 1999(11): 1820-1822
DOI: 10.1055/s-1999-2935
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Preparation and Reactions of Functionalized Magnesium Carbenoids

Salvatore Avolio* , Christophe Malan, Ilan Marek, Paul Knochel
  • *Institut für Organische Chemie der Ludwig-Maximilians-Universität, Butenandtstraße 5-13, D-81377 München, Germany; Fax +89-21 80-76 80; E-mail: paul.knochel@cup.uni-muenchen.de
Further Information

Publication History

Publication Date:
31 December 1999 (online)

  PDF Download  Permissions and Reprints All articles of this category

New functionalized magnesium carbenoids bearing an ester function have been prepared via an iodine-magnesium exchange reaction. These new carbenoids react with various electrophiles (60-88% yield). A substituted magnesium carbenoid has been prepared by sulfoxide-magnesium exchange.

carbenoids - Grignard reactions - sulfoxides - iodine-magnesium exchange - polyfunctional organometallics

      >