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Synlett 1999; 1999(6): 695-696
DOI: 10.1055/s-1999-2744
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Synthetic Study of Pinnatoxin A: Intramolecular Alkylation Approach to the G-ring

Aiko Nitta* , Akihiro Ishiwata, Takeshi Noda, Masahiro Hirama
  • *Department of Chemistry, Graduate School of Science, Tohoku University, and CREST, Japan Science and Technology Corporation (JST), Sendai 980-8578, Japan; Fax +81 (22) 2 17-65 66; E-mail: hirama@ykbsc.chem.tohoku.ac.jp
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Publication Date:
31 December 1999 (online)

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The G-ring model (2) of pinnatoxin A (1) has been constructed with complete stereocontrol via an intramolecular alkylation reaction of an epoxy nitrile (3).

pinnatoxin A - stereoselective - intramolecular alkylation - epoxide - nitrile

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