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Synlett 1999; 1999(4): 377-388
DOI: 10.1055/s-1999-2620
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Applications of Non-Organometallic Phosphorus Reagents in Enantioselective Catalysis

Gerard Buono* , Olivier Chiodi, Martin Wills
  • *ENSSPICAM, URA 1410, Réactivité catalyse, Faculté des Sciences et Techniques de StJérome, Univesité Aix-marseille III, Avenue Escadrille Normandie Niemen, 13397 Marseille Cedex, France
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Publication Date:
31 December 1999 (online)

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Although phosphorus containing ligands are commonly employed for enantioselective catalysis as components of organometallic complexes, recent years have seen a steady growth in the use of non-organometallic phosphorus reagents for similar applications. This review highlights some of the recent literature in this area to date, with particular reference to asymmetric reduction and to C-C and C-N bond forming reactions. The review also serves to highlight some areas of potential future development.

enantioselective - catalysis - catalytic - phosphorus - non-organometallic

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