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Synlett 1997; 1997(7): 812-814
DOI: 10.1055/s-1997-5783
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Conversion of α-Anilino Alkenenitriles to Amides by Chemoselective Palladium-Catalyzed Arylations

Chau-Chen Yang* , Huo-Mu Tai, Pei-Jiun Sun
  • *Department of Cosmetic Science, Chia Nan College of Pharmacy and Science, Tainan 717, Taiwan, Republic of China
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Publication Date:
31 December 2000 (online)

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The reactions of α-anilino alkenenitriles with iodobenzene catalyzed by palladium gave amides and benzonitrile. A general mechanism is proposed to explain the chemoselective arylation at the cyano group.

chemoselective - palladium-catalyzed - Heck reaction - arylation - α-anilino alkenenitriles

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