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Synlett 1997; 1997(7): 821-823
DOI: 10.1055/s-1997-5753
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An Efficient Access to (Z)-Vinyltin Acetals via Titanation of the Corresponding Alkynyltins

Valérie Launay, Isabelle Beaudet, Jean-Paul Quintard*
  • *Laboratoire de Synthèse Organique, UMR 6513 du CNRS, Faculté des Sciences et des Techniques de Nantes, 2 rue de la Houssinière, 44072 Nantes Cedex 03 - France, Fax: (33)02.40.74.50.00; E-mail: quintard@chimie.univ-nantes.fr
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Publication History

Publication Date:
31 December 2000 (online)

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Titanation of alkynyltin acetals has been exploited to obtain the corresponding (Z)-disubstituted vinyltins and γ-hydroxy trisubstituted vinyltins, as a single geometrical isomer.

(Z)-vinyltins - titanation - alkynyltins - acetals - allylic alcohols

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