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Synlett 1997; 1997(7): 799-800
DOI: 10.1055/s-1997-5752
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Asymmetric Synthesis of Unsaturated Pipecolic Acid Derivatives

Claude Agami1 , Dominique Bihan, Rémy Morgentin, Cathy Puchot-Kadouri2
  • 1Laboratoire de Synthèse Asymétrique associé au CNRS, Université Pierre et Marie Curie, 4 place Jussieu, 75005 Paris, France, FAX: (33) 01 44 27 26 20; E-mail: agami@ccr.jussieu.fr
  • 2Laboratoire de Synthèse Asymétrique associé au CNRS, Université Pierre et Marie Curie, 4 place Jussieu, 75005 Paris, France, FAX: (33) 01 44 27 26 20
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Publication History

Publication Date:
31 December 2000 (online)

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Two enantiopure pipecolic acid derivatives having an olefinic moiety were synthesized from an intramolecular addition of allyl silanes on an iminium double bond. The iminium moiety was generated via a reaction of chiral β-amino alcohols with glyoxal.

allyl silanes - iminium ions - unsaturated α-amino acids

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