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Synlett 1997; 1997(7): 807-808
DOI: 10.1055/s-1997-5750
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Novel Two-Step Stereoselective Synthesis of (E)-Enamines and 1-Amino-1,3-dienes from Terminal Alkynes

Henri Doucet, Christian Bruneau* , Pierre H. Dixneuf
  • *Laboratoire de Chimie de Coordination et Catalyse, UMR 6509, CNRS-Université de Rennes, Campus de Beaulieu, F-35042 Rennes, France, Fax: 33 2 99 28 69 39; e-mail: bruneau@univ-rennes1.fr
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Publication History

Publication Date:
31 December 2000 (online)

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(E)-Enamines and 1-amino-1,3-dienes have been prepared by reaction of secondary amines with alk-1-en-1-yl acetates resulting from the ruthenium-catalyzed anti-Markovnikov addition of acetic acid to terminal alkynes and enynes.

enamines - 1-amino-1,3-dienes - alk-1-en-1-yl esters - ruthenium catalysis - stereoselective amination

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