Synthesis 1997; 1997(1): 20-22
DOI: 10.1055/s-1997-1500
short paper
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Methoxycarbonyl-Terminated Dendrons via the Mitsunobu Reaction: An Easy Way to Functionalized Hyperbranched Building Blocks

Sigurd Höger*
  • *Max-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128 Mainz, Germany, Fax +496131379100; E-mail: hoeger@mpip-mainz.mpg.de
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Methoxycarbonyl-terminated dendrons can be easily prepared up to the third generation by a convergent approach using the Mitsunobu reaction as the bond-forming step. The advantages of this procedure are that the transformation of the alcohol moiety to a leaving group and its nucleophilic displacement are performed in one pot under mild conditions.

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