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Synthesis 1997; 1997(7): 727-743
DOI: 10.1055/s-1997-1417
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The Synthesis of Dialkyl α-Halogenated Methylphosphonates

Rachel Waschbüsch* , John Carran, Angela Marinetti, Philippe Savignac
  • *Hétéroatomes et Coordination, URA CNRS 1499, DCPH, Ecole Polytechnique, 91128 Palaiseau Cedex, France, Fax +33(1)69333990
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Publication Date:
31 December 2000 (online)

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This article reviews the main synthetic approaches to mono-, di- and trihalogenated methylphosphonates containing fluorine, chlorine, bromine and iodine. It includes some general, widely used methods, such as the Michaelis-Arbuzov, Michaelis-Becker, Kinnear-Perren and Kabachnik reactions, as well as more specific approaches such as oxidative or reductive procedures. Representative experimental procedures are described for each type of compound.

The main synthetic routes to mono-, di- and trihalogenated methylphosphonates are described

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