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Synlett 1996; 1996(4): 337-338
DOI: 10.1055/s-1996-5439
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Asymmetric Synthesis XXIV: Chiral Salen-Titanium Complexes-Efficient Catalysts for Asymmetric Trimethyl Silylcyanation of Benzaldehyde

Weidong Pan, Xiaoming Feng, Liuzhu Gong, Wenhao Hu, Zhi Li, Aiqiao Mi, Yaozhong Jiang*
  • *Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China, Fax: (0086) (028) 5583978
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Publication Date:
31 December 2000 (online)

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Chiral salen-titanium complex was found to be an effective catalyst for the enantioselective silylcyanation of benzaldehyde. The good enantioselectivity was obtained by using 5mol% Ti(IV)(salen) complex 2d as a catalyst.

chiral salen-titanium complex - enantioselectivity - cyanohydrin - catalytically asymmetric synthesis

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