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Synlett 1996; 1996(4): 361-362
DOI: 10.1055/s-1996-5406
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A Facile Synthesis of N-substituted D-arabino-piperidinol Phosphates from the Inositol Phosphate α-Trinositol

Mats Malmberg, Nicola Rehnberg*
  • *Perstorp Pharma, S-284 80 Perstorp, Sweden, fax +46-435-30296
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Publication Date:
31 December 2000 (online)

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Periodate oxidation of 1D-myo-inositol 1,2,6-triphosphate pentasodium salt (α-trinositol) gives the expected cyclic D-arabino-pentodialdose as a mixture of anomers. Reaction with a primary amine and subsequent reduction with sodium borohydride gives the title compounds.

α-trinositol - analogue - inositol phosphate - periodate oxidation - reductive amination - piperidinol

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