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Synlett 1996; 1996(2): 171-172
DOI: 10.1055/s-1996-5363
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Metal Bis(trifluoromethylsulfonyl)amides as Highly Efficient Lewis Acid Catalysts for Acylation Reactions

Koichi Mikami* , Osamu Kotera, Yukihiro Motoyama, Hiroaki Sakaguchi, Masamichi Maruta
  • *Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo 152, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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Metal bis(trifluoromethylsulfonyl)amides such as aluminum, titanium and ytterbium bistrifylamides are first synthesized and shown to be highly effective Lewis acid catalysts for acylation reactions.

Bis(trifluoromethanesulfonyl)imide - Friedel-Crafts acylation - Aluminum bistrifylamide - Titanium bistrifylamide - Ytterbium bistrifylamide

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