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Synthesis 1996; 1996(4): 465-466
DOI: 10.1055/s-1996-4241
short paper
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Regiospecific Synthesis of 6-Alkylated Lumazine Derivatives Using Silylenol Ethers

Mamoru Igarashi, Masaru Tada*
  • *Department of Chemistry, School of Science and Engineering, Waseda University, Ohkubo, Shinjuku-ku, Tokyo 169, Japan, Fax +81(3)32082735
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Publication Date:
31 December 2000 (online)

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The reaction of oxadiazinone with silylenol ethers gave regiospecifically 6-substituted lumazines by an hetero Diels-Alder addition followed by decarboxylation and silanol elimination.

An oxadiazinone condensed with uracil gave 6-substituted lumazines on reaction with silylenol ethers

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