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Synlett 1995; 1995(12): 1274
DOI: 10.1055/s-1995-5237
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Chemistry of Ethanediyl X,S-Acetals 12. Diastereoselective Synthesis of (E) Alkyl Vinyl Ethers

Romualdo Caputo, Luigi Longobardo, Giovanni Palumbo* , Silvana Pedatella
  • *Dipartimento de Chimica Organica e Biologica Università di Napoli Federico II, Via Mezzocannone, 16, I-80134 Napoli (Italy), Fax +39 81 704 1283
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Publication Date:
31 December 2000 (online)

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Trisubstituted ethyl vinyl ethers with (E) configuration and predetermined regiochemistry are easily prepared from carbonyl compounds via their readily available 5,6-dihydro-1,4-oxathiin 1 derivatives that undergo smooth reductive desulfurization by Raney-Ni in dioxane.

Enolethers - Ketones - 1,4-Oxathiins - Desulfurization - (E) Ethyl vinyl ethers

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