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Synlett 1995; 1995(5): 433-434
DOI: 10.1055/s-1995-5004
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Distannoxane-Catalyzed Conversion of Chiral Alcohol to N-[1-(1-Naphthyl)ethyl]carbamate

Junzo Otera* , Yukihiro Fujita, Tsuneo Sato
  • *Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700, Japan
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Publication Date:
31 December 2000 (online)

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Chiral alcohols are smoothly transformed to the corresponding (R)-N-[1-(1-naphthyl)ethyl]carbamates by treating with (R)-1-(1-naphthyl)ethyl isocyanate in the presence of distannoxane catalyst.

distannoxane - chiral alcohol - carbamate - HPLC - optical resolution

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